Planck constant
The gyromagnetic ratio γ is the constant of proportionality between the frequency ν of nuclear magnetic resonance (or electron paramagnetic resonance for electrons) and the applied magnetic field B: ν = γB. It is difficult to measure gyromagnetic ratios precisely because of the difficulties in precisely measuring B, but the value for protons in water at 7002298150000000000♠25 °C is known to better than one part per million. The protons are said to be "shielded" from the applied magnetic field by the electrons in the water molecule, the same effect that gives rise to chemical shift in NMR spectroscopy, and this is indicated by a prime on the symbol for the gyromagnetic ratio, γ′p. The gyromagnetic ratio is related to the shielded proton magnetic moment μ′p, the spin number I (I = 1⁄2 for protons) and the reduced Planck constant.

Q: The gyromagnetic ratio is often difficult to determine due to difficulty accurately determining the value of what?
the applied magnetic field B