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Germany's high-altitude needs were originally going to be filled by a 75 mm gun from Krupp, designed in collaboration with their Swedish counterpart Bofors, but the specifications were later amended to require much higher performance. In response Krupp's engineers presented a new 88 mm design, the FlaK 36. First used in Spain during the Spanish Civil War, the gun proved to be one of the best anti-aircraft guns in the world, as well as particularly deadly against light, medium, and even early heavy tanks.

What war was the FlaK first used in?
Spanish Civil War