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The trial in Manhattan of John Peter Zenger in 1735 helped to establish the freedom of the press in North America. In 1754, Columbia University was founded under charter by King George II as King's College in Lower Manhattan. The Stamp Act Congress met in New York in October 1765 as the Sons of Liberty organized in the city, skirmishing over the next ten years with British troops stationed there.

On what island did Zenger's trial occur?
Answer: Manhattan
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Arizona, south of the Gila River was legally bought from Mexico in the Gadsden Purchase on June 8, 1854. Tucson became a part of the United States of America, although the American military did not formally take over control until March 1856. In 1857 Tucson became a stage station on the San Antonio-San Diego Mail Line and in 1858 became 3rd division headquarters of the Butterfield Overland Mail until the line shut down in March 1861. The Overland Mail Corporation attempted to continue running, however following the Bascom Affair, devastating Apache attacks on the stations and coaches ended operations in August 1861.[citation needed]

What was the name of the deal in which Arizona was bought?
Answer: Gadsden Purchase
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In the context of chemistry, energy is an attribute of a substance as a consequence of its atomic, molecular or aggregate structure. Since a chemical transformation is accompanied by a change in one or more of these kinds of structure, it is invariably accompanied by an increase or decrease of energy of the substances involved. Some energy is transferred between the surroundings and the reactants of the reaction in the form of heat or light; thus the products of a reaction may have more or less energy than the reactants. A reaction is said to be exergonic if the final state is lower on the energy scale than the initial state; in the case of endergonic reactions the situation is the reverse. Chemical reactions are invariably not possible unless the reactants surmount an energy barrier known as the activation energy. The speed of a chemical reaction (at given temperature T) is related to the activation energy E, by the Boltzmann's population factor e−E/kT – that is the probability of molecule to have energy greater than or equal to E at the given temperature T. This exponential dependence of a reaction rate on temperature is known as the Arrhenius equation.The activation energy necessary for a chemical reaction can be in the form of thermal energy.

What is the probability of molecule to have energy greater than or equal to E at the given temperature T?
Answer:
e−E/kT