Green:

The late nineteenth century also brought the systematic study of color theory, and particularly the study of how complementary colors such as red and green reinforced each other when they were placed next to each other. These studies were avidly followed by artists such as Vincent van Gogh. Describing his painting, The Night Cafe, to his brother Theo in 1888, Van Gogh wrote: "I sought to express with red and green the terrible human passions. The hall is blood red and pale yellow, with a green billiard table in the center, and four lamps of lemon yellow, with rays of orange and green. Everywhere it is a battle and antithesis of the most different reds and greens."

Please answer a question about this article. If the question is unanswerable, say "unanswerable". What year did color theory first appear?
unanswerable